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Sustainability

Developing Renewable Bioplastics from Bio-Derived Monomers

Enhancing the efficiency of material processing, utilization, and recycling is pivotal for advancing sustainability in modern society. The objective of this study is to create sustainable methods for converting non-food biomass into recyclable polymers. One key compound, 4,4'-biphenyldicarboxylic acid (BPDA), is used as an additive in copolymer production and as a blending agent to improve the properties of polyester. BPDA was synthesized through the oxidation of 4,4'-dimethylbiphenyl (DMBP), a compound that can be efficiently derived from biomass-sourced 2-methylfuran.

Maximizing Value from Municipal Solid Waste Incineration Ash — Electrochemical and Chemical Methods for Material Recovery

Municipal solid waste incineration (MSWI) plays a critical role in our waste and energy ecosystem by reducing waste volume and generating electricity. However, the economic viability of MSW incinerators is at risk due to declining electricity prices. Meanwhile, MSWI ash represents an untapped resource for valuable compounds, with an embodied value of $100–$400/tonne, contrasted with incurred landfilling expenses (∼$50/tonne). Here, we propose an integrated process utilizing MSWI electricity to power electrochemical and chemical processes for mining MSWI ash.

Measuring Thermodynamic Properties of Ionic Liquids for the Separation of Azeotropic Refrigerant Mixtures

Refrigerants, essential to heating and cooling systems, are estimated to be used in large quantities daily (approximately 850 million kilograms). While advancements on past generations of refrigerants have reduced toxicity and flammability, current hydrofluorocarbon (HFC) refrigerants are being phased out due to their high global warming potential (GWP). Recycling and repurposing HFCs is challenging, as many are azeotropic mixtures that cannot be separated using conventional distillation.

Sugarcane Bagasse as a Strategy for the Sustainable Development of Magnetic Adsorbents for Dye Remediation

This study aimed to evaluate sugarcane bagasse as a precursor for the synthesis of magnetic carbonaceous material (MC) produced at 230 °C via hydrothermal carbonization, followed by an activation process with KOH (1:2 and 1:4; m:m) at 700 °C under a nitrogen atmosphere (MAC). The study assessed the structure, texture, and adsorption capacity of MC and MAC for the dye methylene blue (MB). FTIR analysis was performed to investigate the structural properties, while BET and BJH analyses were conducted to determine the specific surface area and pore volume.