Hazard Reduction

New pathway to bisnoraldehyde (BNA) from waste soya bean residues. The original route to BNA uses heavy metal catalysts that generate toxic waste, which is harmful to human health and the environment. This novel route to BNA from soya bean residues uses bleach and a catalyst cofactor system. This new process generates a nontoxic, aqueous waste stream and recoverable organic solvents that can be reused. The process also avoids toxic reagents.

Four-step synthetic route for ibuprofen production. This company's four-step synthetic route is an alternative to the traditional six-step synthetic route. This new process has 90% atom efficiency compared to the original process with less than 40% atom efficiency. Using anhydrous hydrogen fluoride as a solvent and catalyst reduces the volume of generated waste and increases the reaction's selectivity. Anhydrous hydrogen can also be recovered and reused with 99.9% efficiency.

Plant-based hydrocarbons. Hydrocarbon-based chemicals and fuels are traditionally petroleum-based. This company produces hydrocarbon-based chemical commodities from plant biomass. This process is renewable and works with most carbohydrate feedstock. More specifically, the company uses sustainably raised corn. Corn is used because it draws a lot of carbon dioxide from the atmosphere. The carbohydrate content and protein content in plant biomass are separated. The protein can be used in other industries.

Low-carbon and formaldehyde-free adhesives. Traditional adhesives are phenol-formaldehyde and urea-formladehyde-based, which are derived from petroleum oil. Formaldehyde is a known cause of cancer and is difficult to recycle. Cambond produces carbon-neutral and sustainable adhesives from biomass feedstocks. It is made by bonding waste from the brewing industry and algae with a special linking agent. The process reduces carbon dioxide emissions by 80%. Cambond® Resin can be used for packaging as an alternative to conventional plastics.

Renewable and recyclable thermoset polymers from non-edible biomass. Conventional thermoset polymers are based on petroleum feedstocks and are non-recyclable. SperoSet produces fully recyclable thermoset polymers that are based on non-edible biomass. Because of SperoSet's chemically reversible bonds, it is degradable in organic or aqueous solutions under mild conditions, recyclable with original thermal and mechanical properties, and repairable and weldable through chemical bond exchange reactions. Reversible bonds eliminate the need for metal catalysts or extra monomers in recycling.

Bio-based solvents. These bio-based solvents serve as alternatives to petrochemical-based solvents. They are derived from agricultural crops that are rich in carbohydrates, such as corn, wheat, and beets. These carbohydrates are then purifed and fermented to make bioethanol and others alcohols and combined with esters of lactic acids and other natural acids. They also include fully biodegradable organic co-solvents. These solvets are less toxic, less flammable, and biodegradable. They also contribute less carbon emissions.

Sustainable biopolymers. EcoMer® is a family of VOC-free, bio-based monomers created from glucose derived from sustainable sources. EcoMer can be copolymerized with conventional vinyl monomers to produce polymers that can be used in pressure-sensitive adhesives. EcoStix® —a family of sugar-acrylic, pressure-sensitive adhesives — incorporates EcoMer technology. EcoStix is recyclable and repulpable. EcoSphere® Biolatex® binders are used in the paper and paperboard industry. They are lower cost, better quality, more productive, and superior in performance to traditional binders.

Long-lasting synthetic oils. Conventional oils are not long-lasting, which generates waste oil. Frequently disposing of large quantities of oil is hazardous to human health and the environment due to its composition of lead, nickel, and other heavy metals. AMSOIL's long-lasting oil extends its lifespan to 11 times longer than conventional oils; pairing this oil with an oil analysis program can further extend its life span. AMSOIL achieves this by removing impurities and allowing molecules to slip more easily over one another, reducing energy lost to friction and maximizing fuel economy.

Polyester polyols based on rPET and other recycled components. Resinate® is a product line that uses recycled and renewable materials for high-performance applications in coating, adhesives, and foams. The product, Resinate® EP1000-5.6, is based on rPET (recycled PET) and other recycled components, resulting in 66% recycled content. Resinate® C2051-50 is a modified polyol for the coatings marketplace and contains 50% renewable content.