Biomass

This report assesses the role of bio-based feedstocks in plastic packaging under the EU’s Packaging and Packaging Waste Regulation (PPWR), with a focus on technological development and environmental performance. Although seventeen bio-based polymers are commercially available, they represent only ~1% of the global plastics market and account for just 4–5% of biogenic carbon in the EU chemical sector. Production capacity is concentrated in Asia (55%), followed by North America (17%) and the EU27+3 (14%).

The transition toward a circular bioeconomy demands innovative, sustainable, and efficient technologies for biomass valorization and pulping. Green chemistry strategies, particularly organosolvent pulping pretreatment, are emerging as pivotal solutions to unlock the full potential of lignocellulosic feedstocks. Organosolvent processes employ environmentally benign solvents to selectively fractionate biomass components, enabling the recovery of high-purity cellulose, hemicelluloses, and lignin with minimal environmental footprint.

The development of sustainable packaging materials from agro-industrial by-products supports the transition to a circular bio-economy and offers a viable alternative to petroleum-based plastics. Cocoa shells (CS), a by-product from the chocolate industry, are an abundant source of cellulose with limited industrial use. In this study, cellulose was extracted from CS and chemically converted into carboxymethyl cellulose (CS-CMC), which was then used to formulate bioplastic films plasticized with glycerol or sorbitol.

Chitin, the most abundant aminopolysaccharide, can be found in the exoskeleton of crustacean shells, a major waste product of the fishing industry. The water-soluble derivative of chitin, chitosan, acquired through a process of deacetylation affords derivatization and processability of this natural biopolymer. Traditionally, deacetylation processes utilizing harsh chemical conditions and high energy inputs limiting scalability and sustainable practices. Furthermore, these methods result in depolymerization, presenting low molecular weight fragments.